 In case of Al-killed grades, the steel
bath contains high melting point Al2O3
inclusions which can lead to nozzle
clogging at the continuous caster, poor
transverse mechanical properties after
rolling, bad resistance to HIC and bad
machinability.
The addition of Ca during ladle refining
transforms Al2O3 into(CaO)x(Al2O3)y
which has a low melting point and also
remains globular during rolling, thus
eliminating the above problems.
12[Ca]+11[Al2O3] ¡æ12CaO.7Al2O3+8[Al] |
 Phase-diagram CaO-Al2O3
(click)
|
 Due to the high and stable recovery
of additions practised by way of cored-wire, a very accurate and reproducible steel chemistry can be achieved which
in turn permits to optimize the mechanical properties and / or heat treatment as well
as eliminate rejection or downgrading of heats out of the chemistry specification. Most popular for this purpose are
cored-wires containing carbon, sulfur, manganese, FeTi
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